Stainless steels in ammonia production nickel institute. A study was made to determine relevant growth data and to determine methods to prevent cracking. Stress corrosion cracking of astm a517 steel in liquid. Zinc, copper and brass are some materials that should not be brought into contact with ammonia that contains water because ammonia corrosion can occur. Evaluate the result under microexamination if igscc intergranular stress corrosion cracking is exhibited in the sample tube. Stress corrosion cracking issues in syngas plants that may be. Stresscorrosion cracking of steels in ammonia with.
At low stressintensity levels stage 1, the crack propagation rate increases. The source of corrosive liquid appears to be condensation of benfield vapours at nozzle b1, which had continuously run down the bridle wall. Stress corrosion cracking control measures nist page. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of. Ammonia corrosion can cause stress corrosion cracking in steels. Stresscorrosion cracking has been determined as the cause of failure of carbon steel tanks in agricultural ammonia service. Localized corrosion and stress corrosion cracking of candidate materials for highlevel radioactive waste disposal containers in u. Effect of anhydrous ammonia composition on its ability to cause. Chloride stress corrosion cracking in austenitic stainless. Introduction a release of benfield solution hot potassium carbonate and syngas from the level bridle of the co2 absorber in the ammonia plant resulted in a plant shutdown and subsequently a. Stress corrosion cracking proceeds more rapidly at high temperatures. Brass, ammonia, higher strength, higher stress levels.
Copper alloys see other formats r a d a 0 1 2 872 stress corrosion cracking 3. This type of failure is referred to as stress corrosion cracking scc. During dissolution, a point is reached in which the corrosion inhibitors, hydroxide and nitrite, are diluted below established guidelines, and. Provide employees information pertaining to the hazards of ammonia. Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. Stress corrosion cracking wikimili, the free encyclopedia. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. For the susceptibility to stresscorrosion cracking, the directional variation can be appreciable and must be considered in the design of the fabricated hardware. While it is rare, formed parts can develop fractures after they are placed in service. Condensed ammonia is a corrodent, and in anhydrous state it can cause stresscorrosion cracking of stressed carbon steels or highstrength, lowalloy steels. The probability of scc increased with increased stress level as well as with increased yield strength of the steel. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of stress corrosion can be prevented are ignored. It is the least for the short transverse direction.
At high pressure, corrosive ammonium carbamate may be formed. This may result in ammonia weeping from a crack within the refrigeration system. The cracks are small at the surface but can be deep, worstcase going through the entire thickness of the metal. Stress corrosion cracking issues in syngas plants that may be missed by riskbased assessment stress corrosion cracking has been causing problems in syngas plants since they were first developed and many of these cases have been covered in previous ammonia safety conferences. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. Stress corrosion of steels anhydrous ammonia iffco. Localized corrosion and stress corrosion cracking of. Case study corrosion issues in co2 removal system in ammonia plants 1. Raw material brass compression fittings are manufactured from bar stock, from forged material or as castings. Tests on statically loaded smooth samples tests on statically loaded precracked samples tests using slowly straining samples more detailed information on these tests can be found in chapter 17, evaluation of stress corrosion cracking, in this book, and in ref 1.
Corrosion by caustic sodium or potassium hydroxide at all concentrations is easily handled at room temperature with a variety of metals and alloys, including carbon steels. Cracking has been detected in ammonia storage tanks. For the susceptibility to stress corrosion cracking, the directional variation can be appreciable and must be considered in the design of the fabricated hardware. Again, corrosion alone in the absence of stress does not produce cracking. Effects of ammonia contaminants, such as air, water, carbon dioxide, oil, etc on failure rates were studied. The wol specimens were not effective in predicting stress corrosion cracking in the liquid ammonia environment. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. Control of stress level residual or load and hardness. Overview of stress corrosion cracking scc in water systems. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking.
Chemicals other than water, like ammonia, can induce subcritical crack. Mechanisms of stresscorrosion cracking asm international. Stress corrosion cracking of steel in liquefied ammonia service a. Astm b85801, standard test method for ammonia vapor test for determination susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2001, back to top. Stress corrosion cracking scc in boilers and cooling water. I dont remember any ss except the reformer furnace tubesmanifolds hk40 hp mod. Observations of corrosion product formation and stress corrosion. The mechanism of scc is shown as a simple representation in figure 1. Stress corrosion cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. Stress corrosion cracking behavior of nickel base alloys. Prevention of stress corrosion cracking of carbon steels in.
Stresscorrosion cracking, materials performance and evaluation. By evaluating the storage and handling facilities and practices for liquefied ammonia and by conducting controlled tests, it was determined that stresscorrosion cracking scc was the most likely cause of the failures 2. Four factors, are required before stress corrosion cracking can occur. The formation of cupric complex ions leads to stress corrosion cracking of brass in ammonia solutions. Stress corrosion cracking scc have long occurred for various types of brass and copperbase alloys in aqueous ammonia solutions. Prevention of stress corrosion cracking of carbon steels. Stress corrosion cracking an overview sciencedirect topics. Preparation of high level waste for vitrification involves in part the dissolution of salt cake from the carbon steel storage tanks. For example, copper and its alloys are susceptible to ammonia compounds. Localized corrosion and stress corrosion cracking of candidate materials for high level radioactive waste disposal containers in u. Electrochemistry of stress corrosion cracking of brass. Scc is highly chemically specific in that certain alloys are likel. Stress corrosion cracking scc is defined as the growth of cracks due to the simultaneous action of a.
Ammonia that is mixed with water is not corrosive to iron or steel. Water can be added to the ammonia to help prevent stress corrosion cracking. Literature suney on stress corrosion cracking of cu in. Astm b85801, standard test method for ammonia vapor test for determination susceptibility to stress corrosion cracking in copper alloys, astm international. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in contaminated cooling water service. This mechanism is characterized by corrosion in the microscopic granular composition of a metals surface. However, different forms of localised corrosion, i. Prevention solution for corrosion issues in co2 removal. Stresscorrosion cracking of steels in agricultural ammonia. Electrochemistry of stress corrosion cracking of brass m. The wol specimens were not effective in predicting stress corrosion cracking in. Stress corrosion cracking in brass is usually localised and, if ammonia has been involved, may be accompanied by black staining of the surrounding surface.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress level and ammonia concentration will influence the rapidity of scc in this laboratory evalution under mercurous nitrate test for suspected scc trend. Stress corrosion cracking sco of carbon and alloy steels in liquid ammonia has occurred spasmodically over the last twenty years. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. It can lead to unexpected sudden failure of normally ductile metals subjected to a tensile stress, especially at elevated temperature. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. This literature study was made to identify the boundary conditions for scc of copper in presence of nitrites, ammonia, carbonates and acetates. Mercury stress corrosion cracking of brass components can also occur in service due to contamination from broken thermometers. Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. Effect of anhydrous ammonia composition on its ability to. During dissolution, a point is reached in which the corrosion inhibitors, hydroxide and nitrite, are diluted below established guidelines, and nitrate stress corrosion cracking scc is possible. Stress corrosion cracking international institute of.
Department of transportation regulations provide effective safeguards to prevent this problem through the required use of postweld heat treatment and the use of 0. Stress corrosion cracking the international institute of. Wet acid gas corrosion of the overhead system is accelerated if hcn is also present. Stresscorrosion cracking experiments can be categorized as. Stress corrosion cracking wikipedia republished wiki 2.
This type of cracking is referred to as stress oriented hydrogen induced cracking sohic. Astm b858 062018 standard test method for ammonia vapor. Stress corrosion cracking scc is a phenomenon that occurs occasionally. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking scc in boilers and cooling. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Also tanks for transporting liquid ammonia, like rail tank cars. Ammonia is not corrosive for stainless steel without presence of water or condensate. Ammonia at high temperature has high potential for nitriding metals. See physical and chemical properties of ammonia for more information. Stress corrosion cracking has been determined as the cause of failure of carbon steel tanks in agricultural ammonia service. The depth of the corrosion grooves tapered off as the general benfield liquid level was reached. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels.
These include the composition of the alloy, its metallurgical structure, heat treatment, stress level, anodetocathode. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Ammonia stress corrosion cracking a mmonia stress corrosion cracking scc is the phenomena of cracks being formed in carbon steel in contact with ammonia. Stress corrosion cracking issues in syngas plants that may. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
It becomes increasingly more corrosive with increasing temperature and concentration. The stress level at which the failure occurs is well below the stress required for a mechanical failure in the absence of corrosion. Ammonium chloride these corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen. These include the composition of the alloy, its metallurgical structure, heat treatment, stress level, anodeto cathode. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Oct 21, 2019 stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. A compressive stress does not cause stress corrosion cracking. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc.
Stress corrosion cracking scc is produced by the simultaneous interaction of three essential factors. It can happen at atmospheric liquid ammonia conditions at 33 c, but also at higher temperatures under pressurized ammonia conditions. Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. By evaluating the storage and handling facilities and practices for liquefied ammonia and by conducting controlled tests, it was determined that stress corrosion cracking scc was the most likely cause of the failures 2. Electrochemistry of stress corrosion cracking of brass by. Ammonia and stainless steel, corrosion blacksmith37 materials dec 11 15. Ammonium carbonate added to give appropriate cc2 levels in tests 14 to 16, and. Pdf stress corrosion cracking scc of nickelbased alloys. The tube ruptured due to ductile overload in the result of localised thinning from internal surface corrosion. Stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stress corrosion cracking, stepwise cracking, sulfide corrosion cracking and sulfide stress cracking.
Astm b858 01 standard test method for ammonia vapor test. If co 2 is trapped in the amine regenerator overhead system by ammonia, corrosion can result according to the following reaction. The manufacturing processes will inevitably introduce a level of stress into the finished product, but if the processes are carefully controlled, these low stress levels will not normally be a problem. Stress corrosion tests have been performed on pressure vessel steels. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack.
Astm b858062018, standard test method for ammonia vapor test for determining susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2018, back to top. This may result in a catastrophic failure of bulk storage vessels. The process does not proceeds indefinitely since the attack of cupric complex ion oxide layer occurs at critical copper ion content which leads to decrease in corrosion rate but the cracking continues with the copper ion concentration. It is typically considered resistant to ammonia stress corrosion cracking.
319 94 1214 918 980 689 962 1260 1075 474 663 1099 1154 1412 984 901 1369 625 576 1252 665 1218 1363 806 1302 1313 330 692 610 792 119 921 1555 558 866 44 952 606 1001 913 1344 615 131 1031 546 309 901 943 1412 708 1154